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If I use ctrl for color picking, before my cursor is over mixer palette, then PSS will pick color that is under the color mixer, on canvas (green in example below ) instead of picking color from color mixer. If I press ctrl, when cursor is over color mixer that it works ok, but I wish it worked in first case too:
https://i.imgur.com/7wOvQOY.gifv

My bad. I figured I can use auto_picker icon on color mixer to fix the issue.

Thx for writing the post, though. I had the same problem but somehow wasn't aware of either solution.